Article
Article name Features of the Physical Characteristics of Water Near Zero Degrees Celsius
Authors Bordonsky G.S. Doctor of Physics and Mathematics, the Chief of the Laboratory of Cryogenesis Geophysics, lgc255@mail.ru
Bibliographic description Bordonskiy G. S. Features of the Physical Characteristics of Water Near Zero Degrees Celsius / / Scholarly Notes of Transbaikal State University. 2020. Vol. 15, No. 3. PP. 85-93. DOI: 10.21209/2658-7114-2020-15-3-85-93.
Section MATHEMATICAL MODELS. EXPERIMENT
UDK 544.344.015.3
DOI 10.21209/2658-7114-2020-15-3-85-93
Article type
Annotation The article considers the physical characteristics of water near 0 °C. This question is important because the characteristics of liquid water in the region of 0. . . 4 °C undergo sharp changes. It is assumed that this behavior of the physical properties of water is associated with the influence of its second critical point, located at a temperature of -53 °C and a pressure of 100 MPa. From this point in the pressure-temperature phase diagram, the Widom line emanates, on which fluctuations in density and entropy increase sharply. It is assumed that fluctuations of thermodynamic quantities determine the anomalies in the physicochemical characteristics of water, including in the region of negative pressures. Negative pressures can exist in the pores of hydrophilic sorbents. The found Widom line at negative pressures in the limiting case can reach 0 °C.
Key words cold water, the second critical point, Widom line, anomalies water characteristics
Article information
References 1. Anisimov, М, A, Holodnava i pereohlazhdvonnava voda как neobvchnvj sverhkriticheskij flvuid / / Sverhkriticheskie flvuidy: Teoriva i praktika, 2012, T, 7, A2 2, S. 19-37. 2. Bazaron, U, B. Nizkoehastotnava sdvigovava uprugost’ zhidkostej, Ulan-Ude: Izd-vo BNC SO RAN, 2000. 166 s. 3. Balhanov, V, K,, Bashkuev, Yu. В, О vozniknovenii konvektivnogo toroidal’nogo viIirya v vode Bajkala / / ZHurnal tekhnieheskoj fiziki, 2013. T, 83, vyp. 11. S. 34-38. 4. Bordonskij, G. S,, Krylov, S. D, О prirode koFeevyli obrazovanij na sputnikovyh snimkah ledvanogo pokrova ozera Bajkal / / Issledovanie Zemli iz kosmosa. 2014, A2 4, S. 27-31. 5. Vinogradov, V, V, Issledovanie vskipaniva peregretvh rastvanutyh zhidkostej: avtoref. ... d-ra fiz.-mat. nauk: 01.04,14, Ekaterinburg, 2006. 43 s. 6. Rodionova, N, V, Nablvudenie kobeevyh struktur na Fdu ozera Bajkal s pomosheh’yu sputnikov Sentinel-1 i Sentinel-2 vesnoj 2016-2018 gg. / / Sovremennve problemv distaneionnogo zondirovaniva Zemli iz kosmosa. 2019. T, 16, A2 4, S. 213-221, 7. Starostin, E, G,, Lebedev, M, P, Svojstva svvazannoj vodv v dispersnvh porodah, Chast’ 1. Vyazkost’, dielektrieheskava pronieaemost’, plotnost’, teplovomkost’ / / Kriosfera Zemli. 2014. T. 18, A2 3. S. 46-54. 8. Starr, V, P, Fizika vavlenij s otrieatel’noj vyazkost’vu, M,: Mir, 1971. 130 s. 9. Haken, G. Sinergetika. M,: Mir, 1980. 405 s. 10. Hejuord, A, OtrieateFnye davleniva v zhidkostvah: как zastavit’ ih sluzhit’ eheloveku? / / Uspekhi fizieheskih nauk, 1972, T. 108, vyp. 2. S. 303-317. 11. Abaseal, J. L, F,, Vega, C. Widom Line and the liquid-liquid critical point for the TIP4P/2005 water model / / Journal of Chemical Physics. 2010. Vol, 133. P. 234502-1/8. 12. Alvarenga, A, D,, Grimsditeh, M, Elastic properties of water under negative pressure / / Journal of Chemical Physics. 1993. Vol. 98. No. 11. P. 8392-8396. 13. Angell, C. A, Supercooled water - two phases? / / Nature Materials. 2014, Vol. 13. P. 637-675. 14. Angell, C. A,, Ogumi, M,, Siehina, W, J. Heat capacity of water at extremes of supercooling and superheating / / Journal of Physical Chemistry, 1982, Vol. 86. P. A998- 1002. 15. Bridde, J. W,, Holten, V., Anisimov, M, A, Behavior of supercooled aqueous solution stemming from hidden liquid-liquid transition in water / / Journal of Chemical Physics. 2014. Vol. 141. Is. 7. P. 074504-1/10. 16. Briggs, L, J, Limiting negative pressure of water / / Journal of Applied Physics. 1950. Vol. 2 1 . P. 721-722. 17. Caupin, F, Escaping the no man’s land: Recent experiments on metastable liquid water / / Journal of Non-Crystalline Solids. 2015. Vol. 407. P. 441-448. 18, Chaplin, М, Water structure and science, URL: http://www.lsbu.ac.uk/water/chaplin.html (data obrashcheniya: 26,02,2020), Tekst elektronnyj. 19, Franszese, G., Stanly, H, E, The Widom line of supercooled water / / Journal of Physics, Condensed Matter, 2007, Vol, 19, Is, 20, P, 205126 -1/16, 20, Gallo, P,, Amann-Winkel, K,, Angell, C, A,, Anisimov, M, A,, Caupin, F,, Chakravarty, C,, Lasearis, E,, Loerting, T,, Panagiotopoulos, A, Z., Russo, J,, Sellberg, J, A,, Stanley, H, E,, Tanaka, II.. Vega, Xu, 1... Pettersson, L, G, M, Water: A tale of two liquids / / Chemical Reviews, 2016, Vol, 116, No, 13, P, 7463-7500, 21, Hundle, P, H,, Loerting, T,, Seortino, F, Supercooled and glassy water: Metastable liquid(s), amorphous solid(s), and no-man’s land / / Proceedings of the National Academy of Sciences USA, 2017, Vol, 114, No 51, P, 13336-1/4, (In Engl.) 22, Mishima O, Volume of supercooled water under pressure and liquid-liquid critical point / / Journal of Chemical Physics, 2010, Vol, 133, No, 14, P, 144503-1/6, (In Engl.) 23, Speedy R, J,, Angell C, A, Isothermal compressibility of supercooled water and evidence for thermodynamic singularity at -45 C / / The Journal of Chemical Physics, 1976. Vol. 65. No. 3. P. 851-858. 24, Xu, L.M., Kumar, P,, Buldvrev, S, V,, Chen, S, H,, Pool, P, H,, Seortino F,, Stenlev H, E, Relation between the Widom line and the dynamic crossover in system with liquid-liquid phase transition / / Proceeding of the National Academy of Sciences USA. 2005. Vol. 102. No. 46. P. 16558-1/4.
Full articleFeatures of the Physical Characteristics of Water Near Zero Degrees Celsius