Article
Article name Creation of Catalyst Carriers by Methods of Powder Metallurgy Using Blowing Agents
Authors Zabelin S.F. Doctor of Engineering Science, Corresponding Member of the Russian Academy of Natural Sciences, Professor,, metal@zabspu.ru
Zelenskiy V.A. Candidate of Physics and Mathematics, Leading Researcher,, zelensky55@bk.ru
Ankundinov A.B. Junior researcher, a-58@bk.ru
Gnedovets A.G. Candidate of Physics and Mathematics, Senior Researcher, agg@imet.ac.ru
Bibliographic description Gnedovets A. G., Zabelin S. F., Zelensky V. A., Ankudinov A. B., Creation of catalyst carriers by methods of powder metallurgy using blowing agents // Scholarly Notes of Transbaikal State University. Series Physics, Mathematics, Engineering, Technology. 2018. Vol. 13, No 4. PP. 90-100. DOI: 10.21209/2308-8761-2018-13-4-90-100.
Section MATHEMATICAL MODELS. EXPERIMENT
UDK 544.2
DOI 10.21209/2308-8761-2018-13-4-90-100
Article type
Annotation The analysis of high-porous metal materials (sponges, foams or cellular) with the use of various blowing agents is presented. Two methods of obtaining bulk high-porous nickel carrier catalysts are experimentally investigated: sintering - evaporation process and sintering - dissolution process. The analysis of two technologies for the creation of high-porous materials based on nickel nanopowder obtained by methods of conductor electrical explosion and decomposition of unstable compounds. It is established that the creation of three-dimensional highly porous nickel catalysts with highly developed surface and hierarchical structure of the pore space is possible on the basis of the preliminary pressing of the nanopowders mixtures of metal and blowing agents, followed by sintering metal particles and removal of the blowing agents. At the same time, highly porous material with through porosity of 65-70 % was obtained by sintering-evaporation method using a solid blowing agent; use of nanopowders of nickel with different origin as a feedstock allows us to form a material with a high value of specific surface.
Key words highly porous materials, catalyst carriers, blowing agents, powder metallurgy, nickel nanopowders, pressing, sintering
Article information
References 1. Izaak T. I., Vodyankina О. V. Makroporistye monolitnye materialy: sintez, svojstva, primenenie // Uspekhi himii. 2009. T. 78, № 1. S. 80-92. 2. Sabirova Z. A., Danilova M. M., Zajkovskij V. I., Kuzin N. A., Kirillov V. A., Kriger T. A., Meshcheryakov V. D., Rudina N. A., Brizickij O. F., Hrobostov L. N. Nikelevye katalizatory na osnove poristogo nikelya dlya reakcii parovoj konversii metana // Kinetika i kataliz. 2008. T. 49, № 3. S. 449-456. 3. Alymov M. I., Rubtsov N. M., Seplyarskii B. S., Kochetkov R. A., Zelensky V. A. and Ankudinov A. B. Combustion and passivation of nickel nanoparticles // Mendeleev Commun. 2017. No. 7. Pp. 631-633. 4. Danilova M. M., Fedorova Z. A., Zaikovskii V. I., Porsin A. V., Kirillov V. A., Krieger T. A. Porous nickel-based catalysts for combined steam and carbon dioxide reforming of methane // Applied Catalysis B: Environmental. 2014. Vol. 147. Pp. 858-863. 5. Kranzlin N., Niederberger M. Controlled fabrication of porous metals from the nanometer to the macroscopic scale // Materials Horizons. 2015. Vol. 2, No. 4. Pp. 359-377. 6. Singh S., Bhatnagar N. A survey of fabrication and application of metallic foams (1925- 2017) // Journal of Porous Materials. 2017. Vol. 24. Pp. 1-18. 7. Stanev L., Kolev M., Drenchev B., Drenchev L. Open-cell metallic porous materials obtained through space holders. Part I: Production methods. A review // Journal of Manufacturing Science and Engineering. 2017. Vol. 139, No. 5. Pp. 050801. 8. Stanev L., Kolev M., Drenchev B., Drenchev L. 2017. Open-cell metallic porous materials obtained through space holders - Part II: Structure and properties. A review // Journal of Manufacturing Science and Engineering. 2017. Vol. 139, No. 5. Pp. 050802. 9. Yuan Z. Y., Su B. L. Insights into hierarchically meso-macroporous structured materials // Journal of Materials Chemistry. 2006. Vol. 16, No. 7. Pp. 663-677. 10. Zhang J., Li С. M. Nanoporous metals: fabrication strategies and advanced electrochemical applications in catalysis, sensing and energy systems // Chemical Society Reviews. 2012. Vol. 41, No. 21. Pp. 7016-7031. 11. Zhang F., Yuan C., Lu X., Zhang L., Che Q., Zhang, X. Facile growth of mesoporous Co304 nanowire arrays on Ni foam for high performance electrochemical capacitors // Journal of Power Sources. 2012. Vol. 203. Pp.250-256.
Full articleCreation of Catalyst Carriers by Methods of Powder Metallurgy Using Blowing Agents